The rotationally resolved photodissociation spectrum of mass-selected Ni~ has been observed. Much of the spectrum is congested and perturbed, making the assignment of spectroscopic constants difficult. However, the use of an accidental perturbation in the upper state is shown to simplify the interpr
The bond strength of Ni+2
β Scribed by R.L. Asher; D. Bellert; T. Buthelezi; P.J. Brucat
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 260 KB
- Volume
- 224
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Ni,Ar+ ions generated in a laser-driven plasma/supersonic expansion are photodissociated at different photon energies. This weakly bound ion fragments into primarily Ni: ( +Ar) at 3.0 eV and into Ni' (+Ni t Ar) at 3.5 eV indicating the Ni-Ni+ bond dissociation energy is between these limits.
## Abstract In this review, we present a general overview on the studies carried out on Ni^+β^β and Ni^2+^βcontaining systems in the gas phase since 1996. We have focused our attention in the determination of binding energies in parallel with an analysis of the structure and bonding of the complexe