## Abstract The reactivity in CeO~2~/Ni and LaGaO~3~/Ni systems, which are constituents of intermediate temperature solid oxide fuel cell (IT‐SOFC) anodes, has been investigated both computationally and experimentally. The CALPHAD‐method (CALculating of PHAse Diagrams), employing BINGSS and THERMOC
Thermochemistry, bonding, and reactivity of Ni+ and Ni2+ in the gas phase
✍ Scribed by Otilia Mó; Manuel Yáñez; Jean-Yves Salpin; Jeanine Tortajada
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 843 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0277-7037
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✦ Synopsis
Abstract
In this review, we present a general overview on the studies carried out on Ni^+‐^‐ and Ni^2+^‐containing systems in the gas phase since 1996. We have focused our attention in the determination of binding energies in parallel with an analysis of the structure and bonding of the complexes formed by the interaction of Ni^+^ with one ligand, or in clusters where this metal ion binds several identical or different ligands. Solvation of Ni^2+^ by different ligands is also discussed, together with the theoretical information available of doubly charged Ni‐containing species. The final section of this review is devoted to an analysis of the gas‐phase uni‐ and bimolecular reactivity of Ni^+^ and Ni^2+^ complexes. © 2007 Wiley Periodicals, Inc., Mass Spectrom. Rev.
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