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Thermochemistry, bonding, and reactivity of Ni+ and Ni2+ in the gas phase

✍ Scribed by Otilia Mó; Manuel Yáñez; Jean-Yves Salpin; Jeanine Tortajada


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
843 KB
Volume
26
Category
Article
ISSN
0277-7037

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✦ Synopsis


Abstract

In this review, we present a general overview on the studies carried out on Ni^+‐^‐ and Ni^2+^‐containing systems in the gas phase since 1996. We have focused our attention in the determination of binding energies in parallel with an analysis of the structure and bonding of the complexes formed by the interaction of Ni^+^ with one ligand, or in clusters where this metal ion binds several identical or different ligands. Solvation of Ni^2+^ by different ligands is also discussed, together with the theoretical information available of doubly charged Ni‐containing species. The final section of this review is devoted to an analysis of the gas‐phase uni‐ and bimolecular reactivity of Ni^+^ and Ni^2+^ complexes. © 2007 Wiley Periodicals, Inc., Mass Spectrom. Rev.


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