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The bidentate behaviour of tetrahydroborate towards copper(II) and group(IV) metals in heterobimetallic complexes

✍ Scribed by Khwaja Salahuddin Siddiqi; Fathi Moh'd Amin Moh'd Aqra; Shakeel Ahmad Shah; Saiyid Aftab Ahmad Zaidi

Book ID: 104637867
Publisher: Springer
Year: 1994
Tongue: English
Weight: 181 KB
Volume: 19
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00139099

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✦ Synopsis

New heterobimetallic complexes of the type [Cu(TETA)-(BH4)2 M(BH4)2] (TETA = triethylene tetramine; M = Si, Ge, Sn, Ti and Zr) were prepared by the interaction of [Cu(TETA)C12MC12] with an excess of KBH 4 in THF.

The results indicate that the complexes are nonelectrolytes and the tetrahydroborate group links to the copper(II) atom and the group(IV) metal in a bidentate manner adopting C2,, symmetry.

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