Bidentate bonding mode of tetrahydroborate and nitrite towards copper(II) in open-faced macrocyclic complexes

The bidentate behaviour of tetrahydrobor

The bidentate behaviour of tetrahydroborate towards copper(II) and group(IV) metals in heterobimetallic complexes

✍ Khwaja Salahuddin Siddiqi; Fathi Moh'd Amin Moh'd Aqra; Shakeel Ahmad Shah; Saiy 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 181 KB

New heterobimetallic complexes of the type [Cu(TETA)-(BH4)2 M(BH4)2] (TETA = triethylene tetramine; M = Si, Ge, Sn, Ti and Zr) were prepared by the interaction of [Cu(TETA)C12MC12] with an excess of KBH 4 in THF. The results indicate that the complexes are nonelectrolytes and the tetrahydroborate g