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The Benzotrifluoride–Nitryl Fluoride–Boron Trifluoride Complex

✍ Scribed by OLÁH, G.; NOSZKÓ, L.; PAVLÁTH, A.


Book ID
109591906
Publisher
Nature Publishing Group
Year
1957
Tongue
English
Weight
207 KB
Volume
179
Category
Article
ISSN
0028-0836

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Novel fluoride transfer in the reaction
✍ Naotake Takaishi; Hitoshi Takahashi; Yoshiaki Inamoto 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 237 KB

Reaction of the tricyclic epoxides (la) and (lb) with boron trifluoride etherate leads to fluorohydrins (2a) and (2v derived in the novel fluoride transfer, whereas (lc) undergoes isomerizationto Spiro ketone (3).