## Abstract The kinetics of the reaction of cyclohexene (CH) with an excess of H~2~O~2~ in acetonitrile (AN) at 293 K was studied at variable concentrations of H~2~O~2~ (1.7–13 M), water (1.6–13 M), acids HX (0.2–1.4 M), and salts NaX (0–1.7 M), with HXHClO~4~, H~2~SO~4~, HNO~3~, HPF~6~, __p__‐tol
The behaviour of chemically altered coals in ZnCl2-catalysed reaction with hydrogen and methanol
✍ Scribed by Peter N. Kuznetsov; Jan Bimer; Piotr D. Salbut; René Gruber; Gerald Djega-Mariadassou; Dominique Brodzki; Evgeny Korniyets; Ludmila Kuznetsova; Andrzey Krzton
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 940 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0016-2361
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✦ Synopsis
A series of chemically altered coals was investigated in the reaction with methanol and hydrogen in the presence of ZnClz as a catalyst. Significant beneficial effects were observed when high-rank coals were altered by reductive and reductively methylating pretreatments. The behaviour of altered low-rank brown and subbituminous coals was affected by both the mode of chemical pretreatment and the reaction conditions.
📜 SIMILAR VOLUMES
A kinetic spectrophotometric investigation of the reaction of the hydrogen peroxide anion with methyl p-nitrophenyl sulfate in methanol solvent resulted in the evaluation of the pKa of HOOH in methanol at 25'C as 15.8 f 0.2. Since normal kinetic procedures for the determination of the equilibrium co