Swmary : A series of 2-heterosubstituted 1,3-oxathianes were synthesized and their reactivity toward a strong base, see-butvllithium, was studied. It was shown that see-butyllithium attacked 2-heterosubstituted 1,3-oxathianes in three different ways depending upon the heteroatom at C-2; the removal
✦ LIBER ✦
The Behavior of 2-Substituted-3-hydroxyisoindolinones in the Reaction with sec -Butyllithium
✍ Scribed by Jóźwiak, A.; Ciechańska, M.
- Book ID
- 121857620
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 198 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-152X
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## Abstract We detected and studied CIDNP effects in the reaction of substituted benzyl chlorides with __n__‐butyllithium in hexane (Scheme 1) in various magnetic fields (from 0·5 Oe to about 25,000 Oe). The polarisation of ^19^F nuclei in the reaction of __p__‐F‐benzyl chloride in strong fields ha