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The Beckmann Rearrangement. IX. A Study of Polyphosphoric Acid as a Rearrangement Medium

✍ Scribed by Pearson, D. E.; Stone, R. M.

Book ID
118124886
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
384 KB
Volume
83
Category
Article
ISSN
0002-7863

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## Abstract The formation and the destruction of an intermediate involved in the Beckmann rearrangement of 2,4,6‐trimethylacetophenone oxime have been studied in concentrated trifluoromethanesulfonic acid by kinetic and spectroscopic measurements. Observed (__k__~obs~) and thermodynamic rate consta