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A Fragmentation-Recombination Mechanism for the Beckmann Rearrangement in Strong Acid

✍ Scribed by Hill, Richard K.; Conley, Robert T.; Chortyk, Orestes T.

Book ID
120923927
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
773 KB
Volume
87
Category
Article
ISSN
0002-7863

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## Abstract The formation and the destruction of an intermediate involved in the Beckmann rearrangement of 2,4,6‐trimethylacetophenone oxime have been studied in concentrated trifluoromethanesulfonic acid by kinetic and spectroscopic measurements. Observed (__k__~obs~) and thermodynamic rate consta