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The Baeyer-Villiger Oxidation of Bicyclic Ketones

✍ Scribed by Meinwald, Jerrold; Frauenglass, Elliott

Book ID: 121324815
Publisher: American Chemical Society
Year: 1960
Tongue: English
Weight: 664 KB
Volume: 82
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01504a052

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Environmentally friendly oxidizing agents such as hydrogen peroxide or dioxygen can be used today in catalytic versions of the almost one century old Baeyer-Villiger oxidation with transition metal complexes as catalysts. On the right is a sketch of a possible mechanism for this reaction with a plat