𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Transition Metal Catalysis in the Baeyer–Villiger Oxidation of Ketones

✍ Scribed by Giorgio Strukul

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
232 KB
Volume
37
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

Environmentally friendly oxidizing agents such as hydrogen peroxide or dioxygen can be used today in catalytic versions of the almost one century old Baeyer-Villiger oxidation with transition metal complexes as catalysts. On the right is a sketch of a possible mechanism for this reaction with a platinum catalyst in homogeneous solution.

📜 SIMILAR VOLUMES

Environmentally friendly liquid phase ox
Environmentally friendly liquid phase oxidation: enhanced selectivity in the aerial oxidation of alkyl aromatics, epoxidations and the Baeyer–Villiger oxidation using novel silica supported transition metal ions
✍ Ian C Chisem; Janet Chisem; John S Rafelt; Duncan J Macquarrie; James H Clark; K 📂 Article 📅 1999 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 127 KB 👁 1 views

Active transition metal species (Co, Cu, Cr, Ni or Mn) supported on a chemically modi®ed silica gel are used as heterogeneous catalysts in a range of liquid phase oxidation reactions: alkyl aromatic side chain oxidations, epoxidations of alkenes and Baeyer±Villiger oxidations of linear ketones to es