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The Au/O2 electrode in 1 M H2SO4

✍ Scribed by Sigmund Schuldiner; Murray Rosen

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
540 KB
Volume
19
Category
Article
ISSN
0013-4686

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✦ Synopsis

Open

circuit dependence of potential on oxygen partial pressure as well as potendostatic behavior in O,-and He-saturated solution were determined. Stable hydrogen-oxygen species were formed, but potential-determining reversbility was found only in the potential range from 0.640.7OV (nhe). This equilibrium could be reasonably explained by an 0,/H,02 exchange. Oxygen, H,O,, or other hydrogenoxygen species may affect open circuit potentials and potentiostatic behavior, but analysis of data assuming reversibility or quasi-equilibrium kinetic theory may be justified only between 0.64 and 0.70 V.

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