𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Atmospheric Chemistry of Alkoxy Radicals

✍ Scribed by John J. Orlando; Geoffrey S. Tyndall; Timothy J. Wallington


Publisher
John Wiley and Sons
Year
2004
Weight
51 KB
Volume
35
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Atmospheric chemistry of HFC-134a: Kinet
✍ Trine E. MΓΈgelberg; Jens Sehested; Timothy J. Wallington; Ole J. Nielsen πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 163 KB

tial . However, questions have been raised concerning the environmental impact of trifluoroacetic acid which is formed from HFC-134a in the atmosphere as a result of the following reaction sequence [7 -10]. (1) (2) (3) (4) Reaction (4) produces CF 3 C(O)F which is hydrolyzed to CF 3 COOH after u

Atmospheric reactions of alkoxy and Ξ²-hy
✍ Roger Atkinson πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 137 KB

Under tropospheric conditions, the major alkoxy radical removal processes involve reaction with O 2 , unimolecular decomposition, and isomerization [1 -4]. The alkoxy radical isomerizations proceed by a cyclic transition state and, because of the ring strain involved, the 1,4-H shift isomerizations

Atmospheric chemistry of CF3O radicals:
✍ Timothy J. Wallington; James C. Ball πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 574 KB

A relative rate technique has been used to study the title reaction over the pressure range 100-700 Torr of air at 296 + 2 K. Four different reference compounds (13CO, CH4, CH2FCI, and CD 4) were used. Using k(CF30 + CH 4) = (2.2 -1-0.2) Γ— 10-14 cm 3 molecule-1 s-1 a rate constant of k(CF30 + 03) =

Atmospheric chemistry of CH2FOCH2F: Reac
✍ M. Goto; M. Kawasaki; T. J. Wallington; M. D. Hurley; A. P. Sharratt πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 185 KB

## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ— 10^βˆ’13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ— 10^βˆ’15^ (in un