The assignment of the photoelectron spectrum of sulphur dioxide
β Scribed by Lloyd, D.R.; Roberts, P.J.
- Book ID
- 127079287
- Publisher
- Taylor and Francis Group
- Year
- 1973
- Tongue
- English
- Weight
- 341 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0026-8976
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π SIMILAR VOLUMES
The photoelectron spectrum of carbon tetrafluoride is compared with X-ray emission spectra and with molecular orbital calculations. The ionization energies at 22.2 and 25.1 eV are related to the 2t2 and 2al orbitals, respectively. With this result all "molecular orbital" states of CF$ are identifie
To aidin inteqreting fhe experimental ionizati& potekials CNDO/Z calculatiox~~ gere cassied out asuming that-the ion had the. same geometry as the paren/ free radical. These caIcuI.atio~~ .&owed that theeIectron confiition for ClO, is . ..G b:a: pi: and for ClO; is . ..a. b: 4 with the lowest unoccu