The ionization potentials of CF4 have been determined by photoelectron spectroscopy. and comparison made xlth the values obtained by an INDO-MO calculation. The theoretical calculations are also used to identify the various ionization processes observed experimentally.
On the assignment of the carbon tetrafluoride photoelectron spectrum
β Scribed by Rolf Manne
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 269 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The photoelectron spectrum of carbon tetrafluoride is compared with X-ray emission spectra and with molecular orbital calculations. The ionization energies at 22.2 and 25.1 eV are related to the 2t2 and 2al orbitals, respectively.
With this result all "molecular orbital" states of CF$ are identified except-the 3t2 and It,-states-
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