𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The arylation of nitroalkanes and nitronate salts with aryllead triacetates

✍ Scribed by Robert P. Kozyrod; John T. Pinhey

Book ID
107858324
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
126 KB
Volume
22
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Use of the electrophilic c-arylation by
Use of the electrophilic c-arylation by aryllead triacetates in the construction of synthons for aizoaceae and amaryllidaceae alkaloid synthesis
✍ Darren J. Ackland; John T. Pinhey πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 201 KB

The vinylogous 8-keto esters, ethyl 2-methyl-4-oxocyclohex-2-enecarboxylate (Hagemann's Ester) (4), ethyl 4-oxocyclohex-l-enecarboxylate (7a) and its double bond isomer (7b), undergo regiospecific arylation with aryllead triacetates at Cl; reaction of the mixture of isomers ( 7a) and ( 7b) with aryl

β€˜Alk-l-ynyllead triacetates’ as alk-1-yn
β€˜Alk-l-ynyllead triacetates’ as alk-1-ynyl carbocation equivalents. The Ξ±-alk-1-ynylation of Ξ²-dicarbonyl compounds and nitronate salts
✍ Mark G. Moloney; John T. Pinhey; Eric G. Roche πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 185 KB

The addition of lead tetraacetate to a chloroform solution of alk-l-ynyltrimethylstannane results in the rapid formation of trimethylstannyl acetate and an unstable species, believed to be the corresponding alk-1-ynyllead triacetate, which can effect the rapid a-alkynylation of B-dicarbonyl compound