The Application of the Baker—Venkataraman Rearrangement to the Synthesis of Benz[b]indeno[2,1-e]pyran-10,11-dione.
✍ Scribed by Nopporn Thasana; Somsak Ruchirawat
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Stereochemical Issues Related to the Synthesis of 7,10- 10,16,3':3,4]pyrazino[1,2-b]βcarboline-5,8-diones. -The condensation of iminoethers like (III) with anthranilic acid proceeds with inversion of the tryptophan stereocenter C-16a. Epimerization of the tryptophan center also occurs by acylation