The application of vanadium(I1) as a powerful reducing reagent in flow injection analysis is described. Results are presented for the determination of various organic and inorganic substances. With spectrophotometric detection, based on the absorption by vanadium(II)-EDTA at 350 nm, limits of determ
The application of strongly reducing agents in flow injection analysis: Part 1. Chromium(II) and vanadium(II)
β Scribed by R.C. Schotohrst; J.M. Reijn; H. Poppe; G. Den Boef
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 331 KB
- Volume
- 145
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
Many reagents cannot easily be applied in quantitative analysis, because of their instability under atmospheric conditions. When such reagents are prepared in a flowing stream, their applicability is very promising; for example, in flow injection analysis, a reagent need be stable only for 20-30 s. The application of chromium(I1) and vanadium-(II) in flow injection analysis is described. Nitrate and nitrite can be determined in the concentration range 5 x 1 O-5-5 x 10". Calibration graphs show good linearity.
π SIMILAR VOLUMES
The application of silver(I1) as a powerful oxidizing reagent in flow injection analysis is described in detail. Under the experimental conditions, the half-life of the very unstable silver(II) was about 120 s. Nevertheless, various organic and inorganic substances could be determined. Spectrophotom