The anodic pyridination of 9,10-diphenylanthracene in acetonitrile: The spectroelectrochemical view
โ Scribed by Henry N. Blount
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 204 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-0728
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โฆ Synopsis
DPA and pyridine concentrations were determined spectrophotometrically at 393.5 nm and 256.5 nm respectively. Concentrations of DPA were accurately known and were of the order of 1 mM.
๐ SIMILAR VOLUMES
On the basis of matching theoretical working curves to experimental data for chronoamperometry of the anodic pyridination of 9,10-diphenylanthracene (DPA) in acetonitrile, Marcoux 1 criticized our assignment of the e.c.e, mechanism to this reaction and suggested that disproportionation to the dicati
Measurements of the quantum yieId of 9,lO-diphcnyIanthracene autoperosidation as a function of dissolved osygtzn concentration in benzene at 25'C are consistent with an intersystem crossin yield of 0.13 + 0.03 for this molecule 2nd the absence of the Spiro-~Ilo~v~d esothermic process SI f 02 3X + TI