The anodic oxidation of some olefins has been investigated at platinum and carbon rod anodes at 25Β°C. Polarographic investigation in acetonitrile shows that highly conjugated olefins (polyenes) are oxidized in reversible l-e oxidation waves, whereas the other olefins show irreversible 2-e oxidation
The anodic oxidation of aqueous solutions of acetate ions at smooth platinum electrodes: Part 1. The non-steady state of oxidation of platinum
β Scribed by M. Fleischmann; J.R. Mansfield; Lord Wynne-Jones
- Publisher
- Elsevier
- Year
- 1965
- Weight
- 885 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0368-1874
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The anodic evolution of oxygen was investigated on the platinum oxide electrode, prepared by a thermal decomposition method, in alkaline solutions; the overvoltage data were reproducible on this electrode. On the basis of reliable mechanistic observations, the most probable path under Langmuir condi
The rates of growth of anodic oxide films at PI m acid and alkahna solutions and Ni III alkaline solutibns are compared. In acid solutions, the rates are pH independent. In alkaline solutions. they are affected by pH. The exchange current densities, i,, in alkaline solutions increase one decade as p