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The aminolysis of N-hydroxysuccinimide esters. A structure-reactivity study

✍ Scribed by Cline, Gary W.; Hanna, Samir B.

Book ID
118022952
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
631 KB
Volume
109
Category
Article
ISSN
0002-7863

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The reactions of a series of secondary alicyclic amines with 4-methylphenyl and 4-methoxyphenyl chloroformates are subjected to a kinetic investigation in water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess, pseudo-first-order rate coefficients (k obs ) are found for all reactions. Plot