The aluminium chloride-catalysed addition P(III) halides to carbonyl compounds
โ Scribed by K.L. Freeman; M.J. Gallagher
- Book ID
- 104250119
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 237 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Abatraet: La(III) 18 a good catalyst for the add~bon of hydroxyl compounds to unsaturated carboxyhc actds, yteldmg ethqolycarboxylates The La(M) can be apphed BS the chloride. the alkoxlde, or the ox& In the latter case m ntu convermon to the La(IJl) salt of the unsahlrpted carboxyhc actd u rcqmted
We have been interested for some time in the nucleophilic addition reactions to carl-6 bony1 compounds , the interpretation of our kinetic data has lead us to conclude that the position of the transition state along the reaction coordinate is not the same for all reactions and depends instead upon t