Syntheses and rearrangement reactions of
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Marion Reuter; Heike Michael-Schulz; Dieter Lentz
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Article
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1991
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Elsevier Science
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English
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Nonacarbonyl-bis(ps-fluoronethylidyne)triiron reacts with alkynes in very regioselective carbon-carbon bond formation forming diferra-allyl-clusters, Fe3 (CO)8 (u3-CF) (~a-CF-CR-CR'). These capped nido cluster compounds undergo thermal isomerization to the corresponding ferrol clusters. In addition