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The allyl-type rearrangement in reactions of tribenzylboron

โœ Scribed by Yu. N. Bubnov; B. M. Mikhailov


Book ID
112421231
Publisher
Springer
Year
1970
Tongue
English
Weight
61 KB
Volume
19
Category
Article
ISSN
1573-9171

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Syntheses and rearrangement reactions of
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Nonacarbonyl-bis(ps-fluoronethylidyne)triiron reacts with alkynes in very regioselective carbon-carbon bond formation forming diferra-allyl-clusters, Fe3 (CO)8 (u3-CF) (~a-CF-CR-CR'). These capped nido cluster compounds undergo thermal isomerization to the corresponding ferrol clusters. In addition