✦ LIBER ✦

The aggregation behaviour of two structurally isomeric glycolipids

✍ Scribed by George S. Attard; Wesley P. Blackaby; Andrew R. Leach

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 547 KB
Volume: 74
Category: Article
ISSN: 0009-3084
DOI: 10.1016/0009-3084(94)90114-7

No coin nor oath required. For personal study only.

✦ Synopsis

The two structurally isomeric glycolipids N-octyl-(l-hexadecylamido)-B-D-glucopyranoside (GIc-N-[8/16]) and Nhexadecyl-(l-oetylamido)-/3-D-glucopyranoside (Glc-N-[16/8]) were synthesized. The lyotropic phase behaviour of these isomers was investigated in order to determine the extent to which the relative disposition of the alkyl chains with respect to the amide unit affects the aggregation properties of the amphiphiles. Both isomers exhibit lamellar and inverse topology cubic mesophases. The extent and polymorphism of the non-lamellar phases appear to be more pronounced in the GIc-N-[8/16] isomer relative to the GIc-N-[16/8] isomer. A molecular mechanics study was undertaken in an attempt to rationalize this behaviour.

📜 SIMILAR VOLUMES

Structural analysis of oligosaccharide c

Structural analysis of oligosaccharide chains of glycolipids by two-dimensional NMR

✍ Fuyuhiko Inagaki 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 718 KB

## Abstract Coherence transfer methods, such as multiple‐relayed COSY and homonuclear Hartman–Hahn spectroscopy, were applied to extract subspectra of constituent monosaccharides, which allowed complete assignments of the proton resonances of oligosaccharide chains of glycolipids. The chemical stru

Structure of the oligosaccharides from m

Structure of the oligosaccharides from mammalian glycolipids

✍ J. Kawanami; T. Tsuji 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 548 KB

Threshold effects on the lectin-mediated

Threshold effects on the lectin-mediated aggregation of synthetic glycolipid-containing liposomes

✍ Rando, Robert R. ;Bangerter, Faan Wen 📂 Article 📅 1979 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 749 KB

Cholesterol analogs containing sugar residues linked by spacer groups to the cholesterol 0 can be incorporated into egg yolk lecithin small unilamellar liposomes. The synthetic glycolipid analogs distribute evenly on both sides of the bilayer. These liposomes are aggregated by the appropriate lectin

Synthesis, structure and fluxional behav

Synthesis, structure and fluxional behaviour of isomeric bis(trimethylstannyl)dihydropentalenes

✍ Yu.A. Ustynyuk; A.K. Shestakova; V.A. Chertkov; N.N. Zemlyansky; I.V. Borisova; 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 913 KB

Structure elucidation of an unusual glyc

Structure elucidation of an unusual glycolipid by two-dimensional N.M.R. methods

✍ L. Weber; J. Stach; G. Haufe; R. Hommel; H.-P. Kleber 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 231 KB

Solution-Structure and Aggregation Behav

Solution-Structure and Aggregation Behavior of Two Dilithiostyrene Derivatives

✍ Harald Günther; Oswald Eppers; Heike Hausmann; Dietmar Hüls; Hans-Egbert Mons; K 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 893 KB

The solution structure and the aggregation behavior of (E)-2-lithio-l-(2-lithiophenyl)-l-phenylpent-l-ene (1) and (Z)-2-lithio-l-(24ithiophenyl)ethene (2) were investigated by one-and two-dimensional 'H-, I3C-, and 6Li-NMR spectroscopy. In Et@, both systems form diniers which show homonuclear scalar