Negative ion photoelectron spectra are reported for the heteronuclear alkali dimer and trimer anions, NaK-, KRb-, KCs-, RbCs-, Na$-, and KzCs-at 488 nm. In addition to assigning all ofthe electronic transitions observed in the mixed dimer anion spectra, vertical detachment energies, adiabatic electr
β¦ LIBER β¦
The adiabatic ionization potentials of the alkali dimers Na2, NaK and K2
β Scribed by Samuel Leutwyler; Manfred Hofmann; Hans-Peter Harri; Ernst Schumacher
- Book ID
- 107732629
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 358 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
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The relevant interstate b 3 βΈ, A 1 βΊ q , c 3 βΊ q , and B 1 βΈ spin-orbit induced Ε½ 2 . Ε½ 2 . matrix elements, arising from the Na 3 S K 4 P manifold are treated within the full J Ε½ . microscopic BreitαPauli approximation based on ab initio configuration interaction CI wave functions. The determinatio