## Abstract The additivity of chloro and hydroxy substituent effects on the formyl proton spin‐spin coupling constants with the __meta__ ring proton, ^5^__J__(HH), has been tested with 15 chlorinated benzaldehydes and hydroxybenzaldehydes by multiple linear regression analysis. No general additivit
✦ LIBER ✦
The additivity of substituent effects upon J(FF) in polysubstituted fluorobenzenes: An update
✍ Scribed by Victor Wray; David N. Lincoln
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 166 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Substituent effects upon ^3^J(FF) are demonstrated to be additive, and a previous analysis of ^4^J(FF) and ^5^J(FF) in polysubstituted fluorobenzenes is updated.
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## Abstract The aromatic ^1^H NMR shifts of __ortho__‐disubstituted benzenes were used to derive 285 pair‐induced chemical shifts (pairwise corrections) for vicinal pairs of the substituent set (F, Cl, Br, I, NH~2~, NHCOMe, NO~2~, OH, OMe, Me, CHO, COMe, CN, Ph). Using these parameters and a simple