The Addition of Hydrogen Halides to cis - and trans -2-Pentene
โ Scribed by Kharasch, M. S.; Walling, Cheves.; Mayo, Frank R.
- Book ID
- 125952983
- Publisher
- American Chemical Society
- Year
- 1939
- Tongue
- English
- Weight
- 622 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained
The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ฯญ Aะ T n exp(ฯช E a ะ/RT) with Aะ ฯญ (1