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The Addition of Hydrogen Halides to cis - and trans -2-Pentene

โœ Scribed by Kharasch, M. S.; Walling, Cheves.; Mayo, Frank R.


Book ID
125952983
Publisher
American Chemical Society
Year
1939
Tongue
English
Weight
622 KB
Volume
61
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


H2S-promoted thermal isomerization of ci
โœ D. Perrin; C. Richard; R. Martin ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 457 KB

H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained

Temperature dependence of the rate const
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The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ฯญ Aะˆ T n exp(ฯช E a ะˆ/RT) with Aะˆ ฯญ (1