Additional Data on the cis and trans Isomers of Pentene-2
β Scribed by Sherrill, Mary L.; Matlack, Elizabeth S.
- Book ID
- 127282425
- Publisher
- American Chemical Society
- Year
- 1937
- Tongue
- English
- Weight
- 547 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained
## Abstract The behavior of the readily available __cis__β (**1**) and __trans__β (**2**) 4, 5βepoxyβ2βpentenals toward classical cationic, anionic, and free radical initiators has been examined. Only the cationic polymerization of **1** gave soluble polymer of moderate molecular weights. This poly