The addition of dimethylsilylene to cyclooctatetraene
β Scribed by Thomas J. Barton; Michel Juvet
- Book ID
- 104224383
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 219 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
CARBENES and nitrenes very rarely add to polyenes in a 1,4 fashion, only two such cases having been reported to date. 233 Presently, we briefly demonstrate that one of the primary products in the reaction of thermally generated (ca 80") dicyanocarbene with cyclooctatetraene (COT) is in fact a 1,4 ad
60]Fullerene reacted with cyclooctatetraene as a dienic partner in the Diels-Alder reaction to give the 1:1 cycloadduct in satisfactory yield (51%), which was attained by heating at relatively low temperature (110Β°C) and for an extended period (2 days). The cycloadduct underwent electrophilic additi