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Diels–Alder reaction of [60]fullerene with cyclooctatetraene and electrophilic addition to the cycloadduct

✍ Scribed by Hiroshi Ishida; Kenichi Komori; Kenji Itoh*; Masatomi Ohno


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
69 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


60]Fullerene reacted with cyclooctatetraene as a dienic partner in the Diels-Alder reaction to give the 1:1 cycloadduct in satisfactory yield (51%), which was attained by heating at relatively low temperature (110°C) and for an extended period (2 days). The cycloadduct underwent electrophilic addition reactions in a manner somewhat different from the usual reactions.


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ChemInform Abstract: Diels—Alder Reactio
✍ Hiroshi Ishida; Kenichi Komori; Kenji Itoh; Masatomi Ohno 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

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