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✦ LIBER ✦
Diels–Alder reaction of [60]fullerene with cyclooctatetraene and electrophilic addition to the cycloadduct
✍ Scribed by Hiroshi Ishida; Kenichi Komori; Kenji Itoh*; Masatomi Ohno
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 69 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
60]Fullerene reacted with cyclooctatetraene as a dienic partner in the Diels-Alder reaction to give the 1:1 cycloadduct in satisfactory yield (51%), which was attained by heating at relatively low temperature (110°C) and for an extended period (2 days). The cycloadduct underwent electrophilic addition reactions in a manner somewhat different from the usual reactions.
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