The Addition-Chlorination of Phenol 1
β Scribed by ROSEN, IRVING; STALLINGS, JOHN P.
- Book ID
- 125501692
- Publisher
- American Chemical Society
- Year
- 1959
- Tongue
- English
- Weight
- 493 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The preparation of [U-14C] 2,4-dichlorophenol was formerly achieved by a Sandmeyer reaction with p-'4C] 2,4-dichloroaniline but this sensitive step gave unreproductive yields in our hands. We describe another route to [U-I4C] 2,4-dichlorophenol by the oxidative chlorination of !J.J-I4C] phenol. Thi
## Abstract In the course of preparing 2 :4 dichlorphenol as an intermediate on a semiβtechnical scale by the chlorination of molten phenol (100%), the possibility of large scale production was considered, with its attendant difficulties of keeping large stocks of the raw material warm enough to re