The Active Intermediates of Non-Heme-Iron-Based Systems for Catalytic Alkene Epoxidation with H2O2/CH3COOH

ChemInform Abstract: Highly Efficient Al

ChemInform Abstract: Highly Efficient Alkylation of Epoxides with R3Al/H2O Systems Based on the Double Activation of Epoxy Oxygens.

✍ Noriko Abe; Hideo Hanawa; Keiji Maruoka; Minoru Sasaki; Masaaki Miyashita 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Highly Efficient Alkylation of Epoxides with R 3 Al/H 2 O Systems Based on the Double Activation of Epoxy Oxygens. -Trialkylaluminum reagents [cf (II)] modified with substoichiometric amounts of water are found to be superior for the alkylative ring opening of epoxides such as (I) and (VI). Bidenta