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The activation of nickel-thiolate complexes towards oxidation by dioxygen

โœ Scribed by M.Y. Darensbourg; P.J. Farmer; I. Font; M.J. Maguire; J.H. Reibenspies

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
82 KB
Volume
51
Category
Article
ISSN
0162-0134

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Much attention has been paid to the oxidation of water to dioxygen by homogeneous catalysts. Of particular interest are di-and tetranuclear transition metal complexes, since extended X-ray absorption fine structure studies have indicated that the O 2 -evolving center (OEC) in photosystem II is compo