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Kinetic studies of the activation of dioxygen by a series of copper(I)-complexes

✍ Scribed by M. Becker; S. Schindler

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
43 KB
Volume
59
Category
Article
ISSN
0162-0134

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Stabilization of the bis(ΞΌ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]-N-[(2'-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring