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The action of sec-aliphatic amines on benzofuroxans

✍ Scribed by D.W.S. Latham; O. Meth-Cohn; H. Suschitzky

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 154 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85251-5

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✦ Synopsis

Various nucleophiles have been shown to react with benzofuroxans (1) by initial attack at the 3-position , offering synthetic routes to heterocycles' including quinoxaline, phenazine and benzimidazole derivatives. The useful reactions of nitrogen nucleophiles are limited to cases resulting in substitution in the homocyclic ring2 or reduction to o-benzoquinonedioxime and o-phenylenediamine2. We now report the ready interaction of benzofuroxans and cold, neat Aec-aliphatic amines (2) to give o-nitrophenyl-

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