๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The acid-catalyzed hydrolysis of 3-oxetanols : An hydroxymethyl group migration in the conversion of 2,2,3-trimethyl-3-oxetanol into 3-methyl-3-hydroxymethyl-2-butanone

โœ Scribed by J. Kagan; J.T. Przybytek


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
418 KB
Volume
29
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Possible neighbouring group participatio
โœ Michael J. Donaghy; Stephen P. Stanforth ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 79 KB

The alcohol 12 reacted with 4-toluenesulfonyl chloride in boiling dichloromethane solution to give the chlorinated product 13 rather than the expected tosylate 3 by a mechanism that could involve neighbouring group participation of the nitro-substituent. In contrast, the isomeric alcohol 15 reacted