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The acetolysis of 4-phenyl-1,3-dioxan. A new synthesis of cinnamyl esters

✍ Scribed by A. Heslinga


Book ID
104586060
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
274 KB
Volume
78
Category
Article
ISSN
0165-0513

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✦ Synopsis


Abstract

The synthesis of 3‐phenyl‐2‐oxa‐1,5‐pentanediol diacetate is given. This compound offers a new route to the preparation of cinnamyl esters.


πŸ“œ SIMILAR VOLUMES


The Hydrogenolysis of 4-Phenyl-1,3-dioxa
✍ Emerson, William S.; Heider, Rudolph L.; Longley, Raymond I.; Shafer, Theodore C πŸ“‚ Article πŸ“… 1950 πŸ› American Chemical Society 🌐 English βš– 272 KB
An improved synthesis of (4S,5S)-2,2-dim
✍ Ivan C. Nordin; James A. Thomas πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 99 KB

The title compound is prepared in 78% yield using an improved one-pot procedure which does not require final purification. The title compound (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine ( 1) is an effective reagent for the synthesis of optically active amino acids (2)l and d-methyl amino acids