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The Absolute Configuration of Dibromopalau'amine

✍ Scribed by Uwe M. Reinscheid; Matthias Köck; Christine Cychon; Volker Schmidts; Christina M. Thiele; Christian Griesinger

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
225 KB
Volume
2010
Category
Article
ISSN
1434-193X

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## Abstract The CD. correlation of (3 S, 3′S)‐and (3 R, 3′R)‐actinioerythrol diacetate, obtained by total synthesis from β‐ionone, with actinioerythrin isolated from the sea anemone Actinia equina L. shows that the natural compound has the (3 S, 3′S)‐configuration.

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## Abstract The absolute configuration of dechlorogilmaniellin (**2**) could be determined from its chiroptical data by applying coupled‐oscillator theory to the CD couplet around 272 nm and from the sign of its n →π^\*^ __Cotton__ effect. Gilmaniellin (**1**) has the same absolute configuration.