## Abstract The absolute configuration of dechlorogilmaniellin (**2**) could be determined from its chiroptical data by applying coupled‐oscillator theory to the CD couplet around 272 nm and from the sign of its n →π^\*^ __Cotton__ effect. Gilmaniellin (**1**) has the same absolute configuration.
✦ LIBER ✦
Absolute Configuration of Actinioerythrin
✍ Scribed by Robert K. Müller; Hans Mayer; Klaus Noack; John J. Daly; James David Tauber; SynnøVe Liaaen-Jensen
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- German
- Weight
- 285 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The CD. correlation of (3 S, 3′S)‐and (3 R, 3′R)‐actinioerythrol diacetate, obtained by total synthesis from β‐ionone, with actinioerythrin isolated from the sea anemone Actinia equina L. shows that the natural compound has the (3 S, 3′S)‐configuration.
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