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The a 1 Δ g → X 3 Σ g- Transition in Molecular Oxygen: Interpretation of Solvent Effects on Spectral Shifts

✍ Scribed by Poulsen, Tina D.; Ogilby, Peter R.; Mikkelsen, Kurt V.


Book ID
126887542
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
94 KB
Volume
103
Category
Article
ISSN
1089-5639

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Mechanism of singlet oxygen interaction
✍ Alexander P. Darmanyan 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 564 KB

The values of relative 0s ('A,) luminescence rate constant (kp ) in thirty-two solvents with ionization potentials IP = 8-l 1 eV are satisfactorily described by a linear dependence of log (kp /n 2, versus IP with a slope of -0.30 eV-i. Singlet oxygen acting as an electron acceptor forms a loose exci