Nitroxyl free radical enhancement of the
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R.E. Belford; G. Seely; D. Gust; T.A. Moore; A. Moore; N.J. Cherepy; S. Ekbundit
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Article
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1993
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Elsevier Science
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English
⚖ 902 KB
Utilizing transient near-IR luminescence spectroscopy, we have shown that free radicals like TEMPO (2,2,6, increase the rate of the forbidden radiative transition of singlet oxygen in chlorinated hydrocarbon solvents. The quantum yield for emission has been shown to depend on the nature of the subst