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The 51Σg+ and 61Σg+ Rydberg States of 7Li2: Observation and Calculation

✍ Scribed by M Song; P Yi; X Dai; Y Liu; Li Li; G.-H Jeung


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
140 KB
Volume
215
Category
Article
ISSN
0022-2852

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✦ Synopsis


The 7 Li 2 5 1 + g and 6 1 + g states have been studied both experimentally and theoretically. Vibrational levels v = 1-26 of the 5 1 + g state and v = 2-14 of the 6 1 + g state were observed using pulsed optical-optical double resonance technique. The 5 1 + g state has an unusual potential energy curve with a shelf near v = 11. Dunham coefficients for the v = 0-9 levels of the 5 1 + g state have been obtained. RKR potential energy curves of these two were generated. Ab initio potentials are in good agreement with the RKR potentials.


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