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The 3400 Å band system of sulphur dioxide

✍ Scribed by R.N. Dixon; M. Hallé


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
382 KB
Volume
22
Category
Article
ISSN
0009-2614

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✦ Synopsis


The contour of the band UC ,502 at 29937 cm -* IIX been SIIOWII to be of type-c, and an approximate excited state structure dcrivcd as rSo = 1.50 A, valence angle = 112". For a number of reasons it is proposed that the princjpal bands between 3150 and 3400 A correspond to vibronicallp induced BI-AI traxitions of R 'Ap-'A1 forbidden clectronic tradition rather than to an allowed 'BI-'A~ transition.


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