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The [2,3]Wittig rearrangement of 2-alkenyloxyacetic acids and its applications to the stereocontrolled synthesis of β, γ-unsaturated aldehydes and conjugated dienoic acids

✍ Scribed by Takeshi Nakai; Kōichi Mikami; Shiro Taya; Yasuhiro Kimura; Tetsuya Mimura


Book ID
111709173
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
270 KB
Volume
22
Category
Article
ISSN
0040-4039

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Application of [2,3]Wittig and [3,3]Clai
✍ Ko¯lchi Mikami; Kazuya Kawamoto; Takeshi Nakai 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 216 KB

An efficient approach to either (22S)-or (22Ij)-hydroxy-23-carboxylic is described which relies on the stereochemical transmission via [2,3]Wittig sigmatropic rearrangement, respectively. acid side chain or [3,3]Claisen