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The 2 1A1 state of cis-hexatriene vapor: Resonance Raman spectra

โœ Scribed by Curtis Westerfield; Anne B. Myers

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
545 KB
Volume
202
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Raman spectra have been obtained on resonance with the 2 'A, state of room temperature cis-1,3,5-hexatriene vapor at 290.8 nm. Overtones and combination bands of totally symmetric stretching and bending modes, both alone and in combination with an interval probably assignable as the overtone of the lowest frequency skeletal bending mode of b, symmetry, are strongly enhanced. Vibrational intervals tentatively assigned to the a2 and b2 methylene torsions are also observed, consistent with a large change in the force constant for =CH2 twisting in the 2 'A, state.

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