The [2 + 1] and [4 + 3] Cyclization Reactions of Fulvenes with Fischer Carbene Complexes: New Access to Annulated Cyclopentanones
✍ Scribed by Barluenga, José; Martínez, Silvia; Suárez-Sobrino, Angel L.; Tomás, Miguel
- Book ID
- 126978488
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 46 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0002-7863
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## Abstract We examined the reactivity of dimethylaminodiazafulvene **1** toward Fischer alkenylcarbene **2** and alkynylcarbene **3** complexes. Diazafulvene **1** reacts with alkenylcarbenes **2** through a formal [6+3] heterocyclization in a regio‐ and stereoselective manner to afford dihydroimi
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