The [2 + 1] and [4 + 3] Cyclization Reactions of Fulvenes with Fischer Carbene Complexes: New Access to Annulated Cyclopentanones.
✍ Scribed by Jose Barluenga; Silvia Martinez; Angel L. Suarez-Sobrino; Miguel Tomas
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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## Abstract We examined the reactivity of dimethylaminodiazafulvene **1** toward Fischer alkenylcarbene **2** and alkynylcarbene **3** complexes. Diazafulvene **1** reacts with alkenylcarbenes **2** through a formal [6+3] heterocyclization in a regio‐ and stereoselective manner to afford dihydroimi
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