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The 147-nm photolysis of monosilane

✍ Scribed by Perkins, G. G. A.; Austin, E. R.; Lampe, F. W.


Book ID
127147000
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
851 KB
Volume
101
Category
Article
ISSN
0002-7863

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## Abstract 1,2‐Fluorochloroethane was photolyzed at 147 nm in the pressure range of 3.8–20.9 torr. The effects of added NO, H~2~S, and large pressures of CF~4~ were also investigated. The exponential extinction coefficient at 147 nm and 296Β°K was found to be 147 Β± 4 atm^βˆ’1^ Β· cm^βˆ’1^. The photoche

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The room temperature photolysis of 1,l-dichloroethane at 147 nm in the pressure range of 1.34-196.2 torr is characterized almost entirely by the molecular elimination of HCl, Cl,, and small quantities of HD. While it is possible that the C2HD arises, in part, from the decomposition of vibrationally

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## Abstract 1,1,1‐Difluorochloroethane (Freon 142) was photolyzed at 147 nm in the pressure range of 3.6–20.6 torr. The effects of added NO, H~2~S, and CF~4~ were investigated. The extinction coefficient at 147 nm and 296Β°K was determined to be 64 Β± 8 atm^βˆ’1^ Β· cm^βˆ’1^. The molecule photodecomposes