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Photolysis of ethyl chloride at 147 nm

โœ Scribed by G. Kramer; A.W. Kirk; E. Tschuikow-Roux

Publisher
Elsevier Science
Year
1976
Weight
199 KB
Volume
5
Category
Article
ISSN
0047-2670

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A vacuum ultraviolet photolysis of C,H,Br at 147 nm was studied over a pressure range of 0.5-50 torr a t 298 K. The effects of additives He and NO were also investigated. The principal reaction products were found to be C,H, and C,H,, with lesser yields of CH, and C,H,. With increasing pressure the

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## Abstract 1,1,1โ€Difluorochloroethane (Freon 142) was photolyzed at 147 nm in the pressure range of 3.6โ€“20.6 torr. The effects of added NO, H~2~S, and CF~4~ were investigated. The extinction coefficient at 147 nm and 296ยฐK was determined to be 64 ยฑ 8 atm^โˆ’1^ ยท cm^โˆ’1^. The molecule photodecomposes