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Thapsigargin, constitution of a sesquiterpene lactone histamine liberator from thapsia garganica

✍ Scribed by S.Brøgger Christensen; Ulla Rasmussen; Carsten Christophersen


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
171 KB
Volume
21
Category
Article
ISSN
0040-4039

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Radiolabelling of the histamine liberati
✍ S. ØGger Br Christensen 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 French ⚖ 252 KB

Thapsigargin ( 1 ) selectively labelled in the butyrate moiety of the molecule was isolated after hydridocarbonyltris(triphenylphosphine)rhodium(I) catalyzed reduction of the product I 5 1 obtained by reacting debutanoylthapsigargin ( 2 ) with 3-butenoic anhydride. The use of tritium gas as a reduci